Table 4 The prominent synchronous correlation cross-peaks for P. vivax infected RBCs and their assignments, 514.5 nm laser line [8,9,10, 15, 22, 27, 34,35,36,37, 41]

2929

ν_s(CH₃); proteins and lipids, PC, outer monolayer₃

ν_s(CH₂); proteins and lipids; PC, outer monolayer

 + (2852,2938)

ν_s(CH₃), PE, internal monolayer

1638

ν_{10; Hz}

amide I (conf-α)

−(1649,2934)

ν_s(CH₃), PC, outer monolayer 

1584

ν₃₇ ; haem; Hz; His, νC₄ = C₅(N_π-H); Asp

ν_19; haem (oxy)

−(1600,2934)

ν_s(CH₃), PC, outer monolayer

1361

ν_4; haem (deoxy); Trp, νN₁ = C₈ (W7); Asp, γ(CH₂)

Lys, δ_s(NH₃⁺); His, νC₄ = C₅ (N_π-, N_τ-);

 + (1527,2936)

ν_s(CH₃), PE, internal monolayer 

Cys, ν(SS)

 +(519,2953)

ν_as(CH₃), out-of-plane, PC, outer monolayer 

Assignment

Cross-peaks

Assignment

His, νC₄ = C₅ (N_π-H), (N_τ-H)

−(1630,1664)

Hz; amide I (conf-β);

ν_as(COO^-), Asp; His, νC₄ = C₅ (N_τ-H)

 + (1574,3186)

2 × ν₃₇

(oxyHb)

ν₁₀; Hz; amide I (conf-α);

−(1639,1696), w

amide I (antiparallel β-sheet),

ν₃₇ ; haem (deoxy)_; His νC₄ = C₅ (N_π-H), δNH;

 + (1581,2943)

ν_s(CH₃), PE, internal monolayer 

ν(CC),  Tyr;

−(1619,1642)

ν₁₀; Hz; amide I (conf-α);

ν₃₇; haem; Asp; His, νC₄ = C₅ (N_π-H), δNH;

 + (1585,1645)

ν₁₀; Hz; amide I (conf-α);

ν_(CC), Tyr; His, νC₄ = C₅ (N_π-H), δNH;

−(1591,1642)

ν_{10; Hz}; amide I (conf-α);

ν₄; haem; Trp νN₁ = C₈ (W7)

 + (1366,1630)

His, νC₄ = C₅ (N_π-H, N_τ-H), δNH

ν(C=C), Tyr; Trp (2 × W18)

 +(1515,1642)

ν₁₀; Hz; amide I (conf-α);

ν₄; haem (deoxy); Trp, νN₁ = C₈ (W7)

 + (1360,1587)

ν₃₇; haem; His, νC₄ = C₅ (N_π-H), δNH

ν_4; haem (deoxy); Trp νN₁ = C₈ (W7)

−(1357,1642)

ν₁₀; Hz; amide I (conf-α);

ν(CO); Tyr, ν_7a’ ν(CO)

 + (1234,1592)

ν(C=C), Gln, δ(NH₂); Trp, W2 

ν₂₁; haem; Ala, δ(CN) 

 +(1300,1642)

ν₁₀; Hz; amide I (conf-α);

ν₃₀; haem (deoxy); Tyr, ν_9a,(CH); δ(COH)

 + (1168,1586)

ν₃₇; haem (oxy); His, νC₄ = C₅ (N_π-H), δ(NH) 

Thr, ω(COO⁻)

−(722,1642)

ν_10; Hz; amide I (conf-α);

ν₂₂; haem (deoxy); Asp, Glu, ν(CO); Thr, τ(NH₃)

 + (1123,1589)

ν₃₇; haem (oxy); His, νC₄ = C₅ (N_π-H), δNH

Cys, ν(SS) 

 +(520,1642)

ν₁₀; Hz; amide I (conf-α);

ν₄₇; haem (deoxy); Phe, ν(CC)

 + (999,1589)

ν(CC); Tyr; His, νC₄ = C₅ (N_π-H), δNH

ν_4; haem (oxy); Trp, νN₁ = C₈ (W7)

−(1372,1519)

ν(C=C),  Tyr-OH; Trp (2 × W18)

Thr, τ(COH); Trp (W18); Val

 + (745,1587)

ν₃₇; haem (oxy); His, νC₄ = C₅ (N_π-H), δ(NH)

ν_4; haem (deoxy); Trp νN₁ = C₈ (W7)

 +(1356,1523)

δ_s(NH₃⁺), Lys

Cys, ν(SS) 

 + (518,1587)

ν₃₇; haem (oxy); His, νC₄ = C₅ (N_π-H), δ(NH)

Cys, ν(SS) 

−(515,1532)

amide II; Lys, δ_s(NH₃⁺); His, νC₄ = C₅ (N_π-, N_τ-);

ν₂₁; haem; Ala, δCN

 +(1289,1376)

Lys, δ_s(NH₃⁺); His, νC₄ = C₅ (N_π-, N_τ-)

Cys, ν(SS) 

 +(519,1373)

Lys, δ_s(NH₃⁺); His, νC₄ = C₅ (N_π-, N_τ-)