Table 6 The prominent 2T2D synchronous and asynchronous EPR correlation cross-peaks and their assignments for P. falciparum and P. vivax infected human whole blood, at 78 K, X-band (expressed as the size of the resonance fields [Gs] and the g-factors)
From: Course of Plasmodium infection studied using 2D-COS on human erythrocytes
Synchronous | Asynchronous | ||||
|---|---|---|---|---|---|
Auto-peaks (g-factor) | Assignment | Assignment | Cross-peaks (g-factor) | Assignment | |
+ (3310) 2.025 | Peroxyl radical | Cu2+-complexes | + (3291,3348) + (2.037, 2.002) | Tyrosyl radical | |
+ (2343) 2.861 | hs Fe3+, non-haem aggregates, linked to protein | Cu2+-complexes | −(3240,3310) −(2.069, 2.025) | Peroxyl radical | |
+ (1656) 4.048 | hs Fe3+, non-haem, in transferrin | hs Fe3+, non-haem aggregates | +(2734,3303) +(2.452, 2.030) | Peroxyl radical | |
+ (1545) 4.340 | hs Fe3+, non-haem, in transferrin | hs Fe3+, non-haem aggregates | −(2531,3360) −(2.648, 1.995) | ls Fe3+, haem | |
Assignment | Cross-peaks (g-factor) | Assignment | hs Fe3+, non-haem aggregates | −(2185,3329) −(3.068, 2.014) | Peroxyl radical |
hs Fe3+, non-haem aggregates | −(2332,3304) −(2.874, 2.029) | Peroxyl radical | hs Fe3+, non-haem, transferin | +(1658,3360) +(4.042, 1.995) | ls Fe3+, haem |
hs Fe3+, non-haem | +(1699,3300) +(3.945,2.031) | Peroxyl radical | hs Fe3+, non-haem, transferin | −(1550,3348) −(4.325, 2.002) | Tyrosyl radical |
hs Fe3+, non-haem, transferin | −(1544,3310) −(4.342,2.025) | Peroxyl radical | hs Fe3+, non-haem, transferin | −(1658,2740) −(4.042, 2.446) | hs Fe3+, non-haem aggregates |